What's the simplest/most concrete vector bundle you can think of that has zero first Stiefel-Whitney class but non-zero second? That would be the simplest space that doesn't have spinors. (See Spin manifold and the second Stiefel-Whitney class) (Which we can interpret as...fermions can't exist?)
It can't be the tangent bundle of a two or three-manifold. (See Vanishing of the second Stiefel–Whitney classes of orientable surfaces and Second Stiefel-Whitney Class of a 3 Manifold ) How complicated do they have to be? What are some examples?
Consider $T\mathbb{CP}^k$, the tangent bundle of $\mathbb{CP}^k$. I claim it satisfies the desired conditions if and only if $k$ is even, in particular, $T\mathbb{CP}^2$ is an example.
There are several ways to see that $w_1(T\mathbb{CP}^k) = 0$ for every $k$:
As for the condition that the second Stiefel-Whitney class be non-zero, we will need the restriction that $k$ is even. To see this, recall that $c(T\mathbb{CP}^k) = (1 + \alpha)^{k+1}$, so $c_1(T\mathbb{CP}^k) = \binom{k+1}{1}\alpha = (k + 1)\alpha$, and hence $w_2(T\mathbb{CP}^k) = (k + 1)\bar{\alpha}$ where $\bar{\alpha}$ is the image of $\alpha$ under the natural map $H^2(\mathbb{CP}^k; \mathbb{Z}) \to H^2(\mathbb{CP}^k; \mathbb{Z}_2)$ induced by the reduction modulo $2$ map $\mathbb{Z} \to \mathbb{Z}_2$. As $\alpha$ is a generator for $H^2(\mathbb{CP}^k; \mathbb{Z})$, it is not divisible by two, so $\bar{\alpha} \neq 0$. Therefore, $w_2(T\mathbb{CP}^k) = (k + 1)\bar{a}$ is non-zero if and only if $k$ is even.