I have expressed the statement "Someone has visited every country except Libya" using quantifiers as follows.
$$\exists x\forall y [V(x, y)\wedge \sim V(x, Libya))]$$ where $V(x, y)$ represents $x$ has visited country $y$.
Is the above representation correct?
Note: Domain for $x$ is all people in this world, and for $y$ is all countries.
No, it is not exactly correct, as pointed out by Michael in the comments. I'd write it as $$\exists x\forall y,\;\lnot V(x,y)\leftrightarrow y=Libya$$