Consider a Lie group endomorphism (bijective homomorphism) $f: G \rightarrow G$ and its pushforward $f_*: \mathcal{A} \rightarrow \mathcal{A}$, where $\mathcal{A}$ is the Lie algebra of $G$. I have seen that if $f$ is an isomorphism (a diffeomorphism) then $f_*$ is an isomorphism.
Is the converse true? That is, given a group endomorphism $f: G \rightarrow G$ with pushforward $f_*: \mathcal{A} \rightarrow \mathcal{A}$ an algebra endomorphism, is it true that if $f_*$ is an isomorphism, the $f$ is an isomorphism too?
As Sebastian Schulz noted, the answer is obviously no if $G$ is not connected.
Furthermore, there are other Lie groups that have isomorphic Lie algebras, but which are not isomorphic since their global properties are different. A well-known example is given by $SU(2)$ and $SO(3)$. The Lie algebras of these groups are isomorphic, but the groups themselves are not: in fact, $SU(2)$ is the double cover of $SO(3)$.