It is given that $M - kI$= \begin{bmatrix}a_{11}&a_{12}\\1&\pi\end{bmatrix}
And I know that for $M$ (which is 2 x 2 matrix), there are two unique eigenvalues such that one of them is $k$.
FYI, I don't have any other info on $a_{11}$ and $a_{12}$. Thanks!
Hint: Since $k$ is an eigenvalue of $M$, $M - kI$ is singular. So that, we have $a_{12} = a_{11}\pi$ and $a_{11}$ is arbitrary. Now, can you find an eigenvector?