I want to make sure I did the steps correctly ;
I got $\alpha = -249, \beta=1.$
$n= 63546| 255$
$x= 255 | 51$
$q= 249 | 5$
$r= 51 | 0$
$i= -249 | 1$
$j= 1 | 0 $
where $255 \times 0 + 51 \times 1 = 51.$ Then $255 \times -249 + 63546\times 1=51$
I want to make sure I did the steps correctly ;
I got $\alpha = -249, \beta=1.$
$n= 63546| 255$
$x= 255 | 51$
$q= 249 | 5$
$r= 51 | 0$
$i= -249 | 1$
$j= 1 | 0 $
where $255 \times 0 + 51 \times 1 = 51.$ Then $255 \times -249 + 63546\times 1=51$
You answer is one of many. Let's first find $\gcd(255,63546)$.
Notice that $255=3 \cdot 5 \cdot 17$ and $63546 = 2 \cdot 3 \cdot 7 \cdot 17 \cdot 89$. Then the highest divisor of these two numbers is $3 \cdot 17$. Hence $\gcd(255,63546) = 51.$
Now it is relatively simple to solve the equation.
\begin{align} 255 \alpha + 63546 \beta & = 51 \\ 5 \alpha + 1246 \beta & = 1 \\ 5\alpha & = 1-1246 \beta \\ \alpha& = \frac{1 - 1246 \beta}{5} \\ \end{align}
Notice that we ended up with a linear equation. Any $\{\alpha,\beta\} \in \mathbb Z$ will work as long as the above equation is satisfied.
Your solution, $\{-249,1\}$ works.
\begin{align} \alpha & = \frac{1-1246 \beta}{5} \\ & = \frac {1-1246 \cdot 1}{5} \\ & = -249 \\ \end{align}
In fact, there are infinitely many solutions to this equation, since it is a linear line and it goes on forever.