you want the line that passes thorough the point $P=(\pi,f(\pi))$, so that it has equation $y-f(\pi)=m(x-\pi)$,
and the slope must be $m=f'(\pi)$.
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First $f(\pi) = \pi (\cos \pi)^2 = \pi$
Now $f'(x) = \cos^2 x - 2x \cos x \sin x = \cos^2 x -x \sin 2x$
So at $f'(\pi) = 1$
So we obtain:
$y=x+b$, now we plug in the value at the point $(\pi ,\pi)$ to obtain:
$\pi = \pi +b$. Hence $b=0$
So we get the line: $y=x$
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Hint:
you want the line that passes thorough the point $P=(\pi,f(\pi))$, so that it has equation $y-f(\pi)=m(x-\pi)$,
and the slope must be $m=f'(\pi)$.