Let $T:\mathbb{R}^3 \to \mathbb{R}^3$ defined as followed: $$T\begin{pmatrix} 3 \\ 2\\ 5 \end{pmatrix}=\begin{pmatrix} 1 \\ 3\\ 2 \end{pmatrix},T\begin{pmatrix} 2 \\ 2\\ 5 \end{pmatrix}=\begin{pmatrix} 0 \\ 1\\ 0 \end{pmatrix},T\begin{pmatrix} 1 \\ 1\\ 3 \end{pmatrix}=\begin{pmatrix} 0 \\ 1\\ 1 \end{pmatrix}$$
If there such a linear transformation find it
What I have done is to to set $$T= \begin{pmatrix} a & b & c\\ d & e & f\\ h & k & l \end{pmatrix}$$
And create linear equations to find that
$$T= \begin{pmatrix} 1 & -1 & 0\\ 2 & -4 & 1\\ 2 & -7 & 2 \end{pmatrix}$$
But $\begin{pmatrix} 1 \\ 3\\ 2 \end{pmatrix},\begin{pmatrix} 0 \\ 1\\ 0 \end{pmatrix},\begin{pmatrix} 0 \\ 1\\ 1 \end{pmatrix}$ is a basis for $\mathbb{R}^3$, and by knowing how the linear transformation work on a basis we can find how it work on any vector, but how can it be done?
$u_1 = \pmatrix{3\\2\\5},u_2 = \pmatrix{2\\2\\5}, u_3=\pmatrix{1\\1\\3}\\ u_1 - u_2 = \pmatrix{1\\0\\0}$
$T\pmatrix{1\\0\\0} = Tu_1 - Tu_2$
Now find $T\pmatrix{0\\1\\0}$ and $T\pmatrix{0\\0\\1}$ and you will have your matrix (in the standard basis.)
Now it would be an option to make $u_1,u_2, u_3$ the basis then you would have to find what $Tu_1,Tu_2, Tu_3$ looks like in this basis.
Or you could make $\begin{pmatrix}1 \\3\\2\end{pmatrix},\begin{pmatrix}0 \\ 1\\0\end{pmatrix},\begin{pmatrix} 0 \\1\\1\end{pmatrix}$ your basis as you suggest but then you will need to find what $u_1, u_2, u_3$ look like in this basis.