Let $R = \{a + b\alpha + c\alpha^2|\ a,b,c \in \mathbb{Z}\}\subseteq \mathbb{C}$ where $\alpha $ is a zero of $ x^3 - 4x +2 = 0$
Is $R$ an integral domain? From my research, I understand that a way to show this is an integral domain is by verifying that it's a subring of C. But am unsure how to proceed.
You have basically said how to do it: as R is a subset of $\mathbb{C}$ all that is left is to show that R is a ring. It contains the unit element 1, so you now need to show that it is closed under addition and multiplication. Addition should be obvious: for multiplication see what happens when you multiply $a+b\alpha+c\alpha^2$ by $d+e\alpha+f\alpha^2$. You can eliminate the $\alpha^3$ and $\alpha^4$ terms by using the fact that $\alpha^3-4\alpha+2= 0$. Then, as you say, it is a subring of $\mathbb{C}$ so it is a domain.