I have been stuck with this problem for so long. I have absolutely no idea how to find the position vector of N. I tried finding the lengths of NC, and AN, but only in vain. I don't think the moduli are going to help me in any way.
I just need help with the method to use to find the position vector of N.
Please help.

Note that since $N$ lies on $AC$ between $A$ and $C$, $AN=2NC$ implies that $\vec{AN}=\frac{2}{3}\vec{AC}.\;$ Thus we have
$\begin{align} \vec{ON} &= \vec{OA} + \vec{AN}\\ &= \vec{OA} + \frac{2}{3}\vec{AC}\\ &= (\mathbf{i}-\mathbf{k}) + \frac{2}{3}(3\mathbf{i}-3\mathbf{j}+3\mathbf{k})\\ &= (\mathbf{i}-\mathbf{k}) + (2\mathbf{i}-2\mathbf{j}+2\mathbf{k})&= \boxed{3\mathbf{i}-2\mathbf{j}+\mathbf{k}}\\ \end{align}$
Equivalently, $AN=2NC$ also implies that $\vec{CN}=\frac{1}{3}\vec{CA}$, and then
$\begin{align} \vec{ON} &= \vec{OC} + \vec{CN}\\ &= \vec{OC} + \frac{1}{3}\vec{CA}\\ \end{align}$
which yields the same result.