What was the first publication of a first-order language that included function symbols, such as the functors of language B of Carnap’s Einführung in die symbolische Logik (1954)?
Function symbols seem to have become commonplace by the mid 1960s -- e.g, Shoenfield's Mathematical Logic (1967) -- but not earlier.
As Mauro ALLEGRAMZA suggested, function symbols ("Funktionszeichen") are introduced in [1], along with the notion of a term. This is a translation by Google Translate from pages 186-187 of the 1968 edition:
According to Heijenoort [2], "In Chapter 3 [of his thesis] Herbrand [3] calls any system a theory if it is obtained from his system of Chapter 2 by the adjunction of some of the following: (1) Function letters (called descriptive functions and intended to represent in the system functions from individuals to individuals) together with an extended rule of existential generalization, ...".
In his 1920 paper [4] (translated to English in [2]), Skolem says:
[1] David Hilbert and Paul Bernays. Grundlagen der Mathematik. 1934.
[2] Jean van Heijenoort. From Frege to Gödel. 1967.
[3] Jacques Herbrand. Reserches sur la théorie de la démonstration. 1930.
[4] Thoralf Skolem. "Logisch-kombinatorische Untersuchungen über die Erfüllbarkeit oder Beweisbarkeit mathematischer Sätze nebst einem Theoreme über dichte Mengen", 1920.