In the FPI method, we are trying to come up with some $g(x)$ such that $f(x)$ can represented as:
$f(x) = x - g(x)$, correct?
What I don't understand is how these translate to: $$ x_{k+1} = g(x_k)? $$ Can someone provide a more intuitive explanation for this?
You have to consider this the other way around. You want some process $x_{k+1}=g(x_k)$ that in each iteration step gets closer to the root of $f$. "Getting closer" includes that the sequence converges, the limit is a fixed point $x^*=g(x^*)$.
Now you need that $x-g(x)=0$ is equivalent to or at least implies that $f(x)=0$, which would be trivially true if $x-g(x)=f(x)$. But usually one takes $g(x)=x-h(x)f(x)$ where $h(x)$ is non-zero in the region under consideration where the root of $f$ is expected. $h$ can be selected to ensure that $g$ is contracting.