For which $n,k > 1$ does $n\mathbb{Z}_k$ have a multiplicative identity?

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By "ring," let us mean a not-necessarily unital ring.

Then $2\mathbb{Z}_6 = \{0,2,4\} \subseteq \mathbb{Z}_6$ and $2\mathbb{Z}_8 = \{0,2,4,6\} \subseteq \mathbb{Z}_8$ are both rings under the induced operations. The former happens to possess a multiplicative identity, namely $4$. The latter does not.

Question. For which natural numbers $n,k > 1$ does the ring $n\mathbb{Z}_k$ happen to possess a multiplicative identity?

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$n\mathbb{Z}_k$ has a multiplicative identity if and only if there is an $a\in \{1,\dotsc,k-1\}$ (we exclude the case $k = 1$ here) such that for all $0 \leqslant b < k$ we have

$$(na)(nb) \equiv nb \pmod{k}.\tag{$\ast$}$$

Write $(\ast)$ in the form $(na-1)(nb) \equiv 0 \pmod{k}$. Setting $b = 1$, we see that the necessary and sufficient condition is the existence of an $a$ with

$$(na-1)n \equiv 0 \pmod{k}.\tag{$\ast\!\ast$}$$

Let $g = \gcd(n,k)$, and write $n = \nu g,\; k = \kappa g$. Then $(\ast\ast)$ becomes

$$(n a-1)\nu \equiv 0 \pmod{\kappa}.\tag{$\ast\!\ast\!\ast$}$$

Since $\gcd(\nu,\kappa) = 1$, that is equivalent to

$$na \equiv 1 \pmod{\kappa},$$

so we find that $n\mathbb{Z}_k$ has a multiplicative identity if and only if

$$\gcd\left(n, \frac{k}{\gcd(n,k)}\right) = 1.$$

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If $n=md$ and $k=hd$ where $m$ and $k$ are coprime, then $n$ must be coprime to $h$.