This is an exercise from Bredon:
Let $X$ be the quotient space of $\mathbb{D}^2$ obtained by identifying points on the boundary that are 120º apart. Find $\pi_1(X)$.
Could you give me any hints on how to proceed?
I tried to apply Van-Kampen's theorem to the sets $U = B(0,1/2)$ and $V = X \setminus \{0\}$, but what is the fundamental group of $V$?

Three points in $\partial D^2 =S^1$ are same. Hence quotient space $\partial D^2/\sim$ is still $S^1$. Hence $\pi_1( \partial D^2/\sim )=\pi_1(S^1)=\mathbb{Z}=(a)$.
But in $X$, curve representing $a^3$ is contractible. Hence $\pi_1(X)=\mathbb{Z}_3$.