The smallest $n$ such that $9n$ uses only the three digits $(0,1,2)$ is $1358$, giving a product $12222$. For $99n$ this is $11335578$, giving $1122222222$. Similarly,
$999(111333555778)=111222222222222,$
$9999(1111333355557778) = 11112222222222222222, ...$
The product seems to be $k$ 1's followed $4k$ 2's for $k$ digit $999...9$. For $n$, this seems to be $1..3...5...7...8$, with $1, 3, 5$ $k$ times and $7$ $k-1$ or $0$ times. Can this pattern be proven and extended for any $k$?
It is readily verified that $$\tag1(10^k-1)\cdot\frac{10^{4k}+2\cdot 10^{3k}+2\cdot 10^{2k}+2\cdot 10^k+2}{9} =\frac{10^{5k}-1}9+\frac{10^{4k}-1}{9}$$ and that the two fractions are in fact integers and the number on the right, being the sum of two repunits, is written with $1$ and $2$ only.
Remains to show that the numbers in $(1)$ are minimal. Note that $(10^k-1)n=10^kn-n$ is the difference of two numbers of different length, so that $10^kn$ (as well as $n$) must start with at least $k-1$ digits $\in\{0,1,2\}$ and the $k$th digit $\in\{0,1,2,3\}$; actually, a $3$ as $k$th digit is only possible if it is followed by a digit $\le 2$ as otherwise no carray (or rather: borrow) orccurs. Also, $(10^k-1)n\equiv -n\pmod{10^k}$ so that the last $k$ digits of $n-1$ must be $\in\{7,8,9\}$. Note that $$\left\lfloor\frac{(10^k-1)n}{10^k}\right\rfloor=n-\left\lceil\frac{n}{10^k} \right\rceil=(n-1)-\left\lfloor\frac{n}{10^k} \right\rfloor$$ so that we conclude about the next $k$ digits: We subtract someting from digits $7,8,9$ and obtain digits $0,1,2$; this is only possible if no borrow occurs, hence the next $k$ digits of $n-1$ are $\in\{5,6,7,8,9\}$. By repeating the argument, the next $k$ digits of $n-1$ are in $\{3,4,5,6,7,8,9\}$. Therefore, $n$ either has more than $4k$ digits, or $n-1$ is described by the regular expression
[12][012]{k-1}[3-9]{k}[5-9]{k}[7-9]{k}. We can exclude the case of more than $4k$ digits as $(1)$ already beats that. Thus we are left with the second case that can also be formulated as: $$ n=\alpha\cdot 4^{3k}+\beta\cdot10^{2k}+\gamma\cdot 10^k+\delta+1$$ where $\alpha,\beta,\gamma,\delta$ are $k$-digit number with digits $\in\{0,1,2\}$, $\in\{3,\ldots,9\}$, $\in\{5,\ldots,9\}$, $\in\{7,\ldots,9\}$, respectively. Then $$(10^k-1)n=\alpha\cdot 10^{4k}+(\beta-\alpha)\cdot 10^{3k}+(\gamma-\beta)\cdot 10^{2k} +(\delta-\gamma)\cdot10^k+(10^k-1-\delta)$$ A stated above, the subtractions $\delta-\gamma,\gamma-\beta,\beta-\alpha$ involve no borrows. Therefore any zero occuring in $\alpha$ would produce a digit $\ge 3$ in $\beta-\alpha$ and hence also in $(10^k-1)n$. We conclude that $\alpha$ contains no zeroes. But then $\alpha \ge 11\ldots 1$, $\beta\ge 33\ldots 3$, $\gamma\ge 55\ldots 5$, $\delta\ge 77\ldots 7$ and ultimately the solution $(1)$ is inded the minimal solution.