Consider a group $S:(\Bbb R\neq 0, \phi)$ consisting of all real numbers except zero, and operation $\phi(v,w)=vw$. Find an automorphism of $S$.
My process: An automorphism $\gamma$ is a bijection such that $\phi(\gamma(v),\gamma(w))=\phi(v,w)$.
Let $\gamma(a)=-a$. So $\phi(\gamma(v),\gamma(w))=\gamma(v)\gamma(w)=(-v)(-w)=vw=\phi(v,w)$
Thus, $\gamma$ is an automorphism of $\phi$. Is this correct? I do not have too much experience in Group Theory so I can't really tell.
Your example is not an automorphism.
For example: (Using $\cdot$ as an infix symbol for $\phi$)
$\gamma(2\cdot 3)=\gamma(6)=-6$; but $\gamma(2)\cdot \gamma(3)=(-2)\cdot (-3)=6$.
Note: An automorphism of a group must send the group identity element ($1$ in this example) to itself.