I have seen the following in my observation. I am so sorry, if I am wrong. I do not know how far I am right. But, I feel that, it might be correct. If correct, Please let me know that way to proceed further to prepare a proof.
every number can be expressible either, prime + prime or prime + non prime or non prime + non prime or non prime + prime as shown below. To support GC, I would like to take an example to show these combination. For example: number 10 (>2) and consider that non prime as NP and prime is P.
10 = 1 + 9 or 2 + 8 or 3 + 7 or 4 + 6 or 5 + 5
I am sure there is prime + prime in every even integer.
We can notice that every integer > 2 can be expressible any one of the above form. If P + P is not taken place in the above example, then there is no question of discussion of GC. Now, find the number of primes in fraction. If the fraction is > ¼, then we need not to discuss further proof of GC. No matter what fraction we have taken, we find the same. If the fraction of primes is 1/8, then the probability of finding N + P are 6/16, but we require 8/16 to avoid any P + P sums. If the fraction of primes is 1/10, then the probability of finding N + P are 8/25, but we require 10/25 to avoid any P + P sums. The probability is always strongly in favor of a P + P. So, we can conclude the GC.
Here: n is non prime and p is prime
Your idea is interesting, but sadly enough we can prove it is no good for a large enough integer $N$. It is very well know that the prime-counting function, $\pi(x)$, which counts how many primes there are less than $x$, is asymptotic to $x/\log(x)$, i.e. $$ \lim_{n \to \infty} \frac{\pi(n)}{n/ \log(n)} = 1. $$ This means that $$ \lim_{n\to \infty} \frac{ \pi(n)}{n} = \lim_{n \to \infty} \frac 1{\log(n)} \frac{\pi(n)}{n/\log(n)} = 0. $$ Therefore, the "fraction" you speak of can be put arbitrarily small, since this fraction goes to $0$ as $n$ goes to infinity. This technique of using a pigeonhole principle argument (using the fact that there are enough primes to counter-balance the non-primes) is therefore quite useless.
In some way, this means that the Goldbach conjecture would hold not because there is enough primes in probability, but because the primes are positioned "at the right spots", in the sense that if we take $N$ large enough and consider a set of $\pi(N)$ numbers (a subset of the first $N$ integers) as special numbers, the probability that two special numbers sum up to $N$ is zero, because $\pi(N)/N \to 0$ as $N$ goes to infinity.
Hope that helps,
(P.S. I don't blame you for thinking about it, it is a cool thing to do, I'm just telling you this is not a good direction. =D )