I am trying to show that a group $G$ of order $60$ with $20$ elements of order $3$ is isomorphic to $A_5$.
I know that $A_5$ is the unique simple group of order $60$. I can conclude if I show that $n_5 = 6$.
I know $n_3 = 10$. I have made multiple attempts, counting arguments don't seem to be working. Most successful so far I showed that if $H$ is a non trivial normal subgroup of $G$, if $3$ divides $|H|$ then $H$ must have order $30$.
I am out of ideas.
I think the following argument works.
Suppose that $n_5 \neq 6$. The only other possible value is $1$, so $n_5=1$. Let $P$ be the unique (i.e. normal) Sylow $5$-subgroup of $G$, and let $Q$ be a Sylow $3$-subgroup of $G$. Since there are exactly $20$ elements of order $3$ in $G$, it follows that $|N_G(Q)|=6$.
But $P$ is normal in $G$, thus it permutes with every other subgroup. In particular, $PQ$ is a subgroup of $G$ and it has order $15$. Now every group of order $15$ is abelian, so $P$ centralises $Q$ and therefore $P \leq N_G(Q)$. This implies that $|P| = 5 \mid 6 = |N_G(Q)|$, a contradiction.
So we see that $n_5=6$, and from this it follows that $G \cong A_5$. (I'm not providing a proof of this last claim because in your question you mention that you know this.)