In the below paper,
Persistent Homology: An Introduction and a New Text Representation for Natural Language Processing
the author provides an visual example of the boundary of a $p$-chain as seen
Definition: The boundary of a $p$-chain is the $+_{2}$ sum of the boundaries of its simplices. The boundary of a $p$-chain is a group homomorphism from the $p$-chain group $C_{p}$ to the $(p-1)$-chain group $C_{p-1}$.
From the visuals, $p = 2$ so the homomorphism map is from $C_{2}$ to $C_{1}$.
What are the elements in $C_{2}$ then? Well, the elements are $2$-chains, by definition of a $p$-chain group.
What is the boundary of a $2$-chain then? Well, the $2$-chain is a subset of $2$-simplices in a simplicial complex. In other words, the $2$-chain is a subset of convex hulls of (2 + 1) points - i.e., subset of triangles.
For each of the $2$ - simplex, the boundary is the set of (2 - 1) - simplices face - i.e., $1$ - simplex face or edges. So a boundary of a $2$ - simplex is the blue triangle on the left. Another boundary of a $2$ - simplex is the blue triangle to the right of it. These two triangles are elements in $C_{2}$.
The definition of a group homomorphism requires that a map from a group $G$ to a group $G'$ be onto an operation preserving.
Since the homomorphism map is onto $C_{1}$ or $1$-chain group, note that a $1$-chain is a subset of $1$ - simplices. The boundary of a $1$-simplex is the set of $0$-simplices faces - i.e., point/ vertex. It appears that arriving at the blue square requires the $+_{2}$ sum of the boundaries of $1$-simplex which a $1$-chain is a subset of. I am unable to proceed. Any help is appreciated.

I understand it is a bit hard without seeing any algebraic topology background. The paper is (out of necessity) very terse as well.
The boundary of a triangle is three edges. In general the boundary of a $p$-simplex is the sum of all of its $(p-1)$-dimensional faces.
The first question is what do I mean by "sum". After definition 15 the author briefly mentions that addition of chains is the modulo 2 addition. There are other options in algebraic topology, but this one is very simple so we stick to it. Note that in this case a chain can be thought of as a sum of simplices, or a set of simplices - it is the same because the sum is just determined by which simplices are there.
Now that we know what a sum is, and we know how to compute the boundary of a simplex, we can also compute the boundary of a chain (that is, of a sum of simplices). If the boundary is supposed to be a group homomorphism then the only thing we can do is
$$\partial(\sigma_1+\sigma_2)=\partial(\sigma_1)+\partial(\sigma_2).$$
In your case let us denote by $\sigma_1,\sigma_2$ the two yellow triangles. Then $\sigma_1+\sigma_2$ is a chain consisting of two triangles (geometrically the square). Let us also denotes by $a,b,c,d$ the sides of that square (blue edges) and by $x$ the diagonal of the square (also blue). Then
$$\partial(\sigma_1)=a+b+x$$ $$\partial(\sigma_2)=c+d+x$$
so
$$\partial(square)=\partial(\sigma_1+\sigma_2)=\partial(\sigma_1)+\partial(\sigma_2) = a+b+x+c+d+x=a+b+c+d$$
because $2x=0$ by our convention. So the "algebraic" boundary of the square is the "geometric" boundary of the square.