Considering to apply the Newton method to find $f$ root, which is the initial value of $x_0$:
\begin{cases} x_{n+1}=x_n-\frac{f(x_n)}{f'(x_n)} \\ x_0=? \end{cases}
Study of the function $f$ on the interval $[0,2\pi]$:
$$f(0) \ f(2\pi)<0$$ $$f'(x)=2x+\sin(x)>0 \qquad \forall x \in [0,2\pi]$$
So: $$\exists! \qquad x^*\in [0,2\pi]: f(x^*)=0$$
Theorem of Newton method convergence: $$sign (x_0-x^*)=sign(f' f'')$$
$$f''(x)=2+\cos(x)$$ $$sign(f' f'')=1$$
$$x_0=2\pi$$
Is it correct?
Thanks!
$x^2-\cos(x)$ is increasing and convex on $[0,2\pi]$, hence if you start Newton's iteration at the right of the only root you get a decreasing sequence converging to your root (with the chance to employ some steps of the secant method in-between to improve the convergence speed). Since $1^2-\cos(1)$ is positive but not that large, it is not a bad idea to start iterating at $x_0=1$.
With few iterations we get that the root is at $\approx 0.8241323123$.