How do I see that $\mathbb{CP}^2$ is not the boundary of a compact smooth $5$-manifold?
There is an answer here for a more general question, but I was wondering if there was a more elementary way of seeing it that solely used techniques developed in Hatcher's Algebraic Topology.
Toward contradiction, assume it is the boundary of a compact 5-manifold $V$. Then the adjunction space $D(V)=V\cup_{\mathbb{C}P^2} V$ is a closed 5-dimensional manifold, so its Euler characteristic vanishes by Poincaré Duality. Thus, by additivity of the Euler characteristic, we have
$$0=\chi(D(V))=2\chi(V)-\chi(\mathbb{C}P^2)=2\chi(V)-3.$$
This gives the desired contradiction.