Consider a vector space $V$ and its double dual $V^{**}$. In general, the space $V^{**}$ is far too large and so we wish to find a coarse topology on it. So we instead only consider those maps that are generated by $V$, that is we only consider maps $\chi \in V^{**}$ such that $$\chi_v(f) = f(v) \quad\forall f \in V^*$$ and require them to be continuous, which is of course the weak* topology on $V^*$.
In most textbooks it is simply stated that we may do such an embedding that defines $\chi_v$ as above, but why is this? How do we know such $\chi_v$ even exist? What do maps look like that are not of this form?
Second, in defining the weak* topology why was the choice made to make these maps in particular continuous? Do they give us some nice property?
For double dual elements not of the form $\chi_v$ for $v\in V$, see https://en.wikipedia.org/wiki/Dual_space#Infinite-dimensional_case. The $\chi_v$ exist simply because we can verify that $\chi_v$ is a well-defined function that is linear, so it lies in $V^{\ast\ast}$. More generally, you can verify that $\Phi\colon V\to V^{\ast\ast}$ defined by $\Phi(v) := \chi_v$ (alternatively written $\Phi(v)(f) := f(v)$) is an injective linear map that preserves the norm on $V$ and $V^{\ast\ast}$ (if they have one), and $\Phi$ is surjective if and only if $V$ is finite-dimensional. You can see https://en.wikipedia.org/wiki/Dual_space#Double_dual for a mention of the weak topology, if that helps.
(Hit character limit in comments so changed to an answer).