I was recently doing a problem, and apparently got it wrong.
The question asked: what is the polar form of the sum: $(5+3i)$ + $(-10-3i)$.
From my understanding, the sum would equal: $-5+0i$
Now,
the magnitude would equal: $\sqrt{-5^2 + 0^2} = 5$
And,
the angle would equal: $\tan^{-1}(\frac{0}{-5}) = 0$
Instead, the answer is actually $5 (\pi)$, instead of $5 (0)$.
I check on this website: 2pif.com (under the "Complex Numbers" tool), and it also says that 5 (0) is the answer.
So I'm wondering, how in the world does $\tan^{-1}(\frac{0}{-5}) = \pi$

This is a common error among new people into the complex numbers. The argument of a complex number $z = a + ib$ is not $\arctan (b/a).$ It is given by $$\arg z = \begin{cases} \arctan (b/a) &\mbox{if } a>0 &\\ \arctan (b/a)+\pi &\mbox{if } a<0,b\geq 0 \\ \arctan (b/a)-\pi &\mbox{if } a<0,b< 0 \\ \pi/2 &\mbox{if } a=0,b> 0 \\ -\pi/2 &\mbox{if } a=0,b< 0 \\ \mathrm{undefined} &\mbox{if } a=0,b= 0 \\ \end{cases} $$