From Wikipedia:
The Catalan number $C_n$ is the number of different ways a convex polygon with $n + 2$ sides can be cut into triangles by connecting vertices with straight lines (a form of Polygon triangulation). The following hexagons illustrate the case $n = 4$:
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Combining triangulations that only differ by rotation or mirroring, how many non-isomorphic ways a convex polygon with $n + 2$ sides can be cut into triangles do we get then?
I currently got: $(1),1,1,3,4$ for $n=1$ to $5$, but I'm unsure how to count the triangle ($n=1$) and if I got all cases for the heptagon ($n=5$).
This type of problem (counting orbits of objects under some symmetry group$~G$, here the dihedral group associated to the $(n+2)$-gon) can be handled using Burnside's lemma, which says that the number of orbits is equal to the average over all group elements $g\in G$ of the number of objects fixed by$~g$. You already know the number of objects (triangulations) fixed by the identity element, namely all $C_n$ of them. The remaining group elements can be partitioned into conjugacy classes since the number of objects fixed by$~g$ is constant as $g$ varies over a conjugacy class. Only a few conjugacy classes will admit any fixed objects at all, which makes counting this way feasible.
To simplify put $m=n+2$, so the we are considering triangualtions of an $m$-gon, and $G=\operatorname{Dih}_m$, the dihedral group of order$~2m$. Among the rotations we need only consider those of order $2$ or $3$, if they exist, since the center of the $m$-gon must either be on an edge of the triangulation or in the interior of a triangle, and that edge/triangle alone limits the possible rotational symmetry of the triangulation to be at most twofold respectively threefold. The reflections in$~G$ form either one or two conjugacy classes (when $m$ is odd respectively even). When $m$ is even, the reflections$~g$ whose axis does not pass through any vertices (but rather through two midpoints of sides) do not admit any triangulations fixed by$~g$, since for either of the sides cut by the axis of the reflection, the third corner of the triangle on that side would have to be a $g$-fixed vertex, which doesn't exist. By the same reasoning, if $m$ is odd, any triangulation fixed by a reflection must contain the (isosceles) triangle defined by the side and the vertex on the axis of the reflection.
Consider the rotation$~z$ of order$~2$, which occurs in$~G$ when $m$ is even. Any triangulation fixed by it must contain exactly one of the $m/2$ diagonals that pass through the center of the $m$-gon. Once this diagonal is chosen, a $z$-symmetric triangulation is determined by a triangulation of one of the two $(m/2+1)$-gons into which the $m$-gon is cut, as the other one must be its image by$~z$; this can be done in $C_{m/2-1}$ different ways. So whenever $m$ is even, $z$ contributes $\frac m2C_{m/2-1}$ triangulations fixed by it. Similarly, whenever $m$ is divisible by$~3$ there are two rotations$~\rho$ of order$~3$; each one fixes the same set of triangulations, but we must not forget to count them twice. A $\rho$-fixed triangulation must contain exactly one of the $m/3$ equilateral triangles that share their center with the $m$-gon. Each such triangle leaves three $(m/3+1)$-gons to be triangulated, but after this has been done for one of them in one of the $C_{m/3-1}$ possible ways, the remaining ones are determined by the required $\rho$-symmetry. So the contribution of $3$-fold symmetry when it exist is $2\frac m3C_{m/3-1}$.
We are left with the reflections. If $m$ is odd there are $m$ conjugate reflections, for each of which as we have seen the axis determines a triangle that must occur in any triangulation fixed by it, and there remain two $(m+1)/2$-gons, of which as before it will suffice to triangulate one, in one of $C_{(m-3)/2}$ possible ways. This contributes $mC_{(m-3)/2}$ whenever $m$ is odd. The final case, with $m$ even and $\sigma$ is one of the $\frac m2$ reflections whose axis passes through two opposite vertices, is the most subtle one. On one hand the axis itself might occur in the triangulation, and this possibility accounts (for all such reflections combined) for $\frac m2C_{m/2-1}$ $\sigma$-fixed triangulations (the same number as contributed by $z$ alone). However the axis of reflection need not occur in the triangulation: it may run through the interior of triangles, and since every edge of the triangulation that meets the axis must be perpendicular to it one sees that there must be exactly two such (isosceles) triangles that cover the symmetry axis. To find the contribution of such symmetric configuration one might sum over all possibilities for this pair of triangles and discover that the result can be simplified by the quadratic recurrence satisfied by the Catalan numbers; one can however jump to the resulting expression by the following trick: the quadrilateral formed by the two triangles covering the axis can be re-triangulated in one other way, and the result is a $\sigma$-fixed triangulation in which the axis does occur. The correspondence is bijective, so we get one more contribution of $\frac m2C_{m/2-1}$.
We summarise, using the Iverson bracket $[d\mid n]$ to denote $1$ when $d$ divides $n$ and $0$ otherwise. The number of configurations for $m=n+2$ is given by $$ f(m)= \frac1{2m}\left(C_{m-2} +[2\mid m]\,\frac{3m}2C_{m/2-1} +[2\not\mid m]\,mC_{(m-3)/2} +[3\mid m]\,\frac{2m}3C_{m/3-1}\right) $$ If you like you can combine the middle two terms in parentheses by $\Bigl(1+\frac{[2\mid m]}2\Bigr)\,mC_{\lfloor m/2\rfloor-1}$ for a somewhat more compact formula. The first few values of this expression, as function of $n$, are $$\scriptstyle \begin{matrix} n & 1&2&3&4&5&6&7&8&9&10&11&12&13&14&15&16 \\ \hline f(n+2)&1&1&1&3&4&12&27&82&228&733&2282&7528&24834&83898&285357&983244 \end{matrix} $$
Once we've got these numbers, it is of course easy to look this up in OEIS. Indeed it is sequence A000207 whose title is "Number of inequivalent ways of dissecting a regular $(n+2)$-gon into $n$ triangles by $n-1$ non-intersecting diagonals under rotations and reflections; also the number of planar $2$-trees".