How many ways can the set of 16 pieces be arranged in 16 squares on the chess board?

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Can someone explain the number theory to me to derive the answer

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I assume you are asking about arranging $16$ chess pieces of the same color anywhere on the board, with no other pieces of the other color on the board at this time.

First we have to choose the $16$ squares that we want to choose to have a piece on it out of the total $64$ so this is $$\binom{64}{16}$$

Next we have to arrange the $16$ pieces (the 8 pawns, 2 rooks, 2 bishops, 2 knights, the queen, and king). This is $$\frac{16!}{8! 2! 2! 2!}$$

Multiplying these two quantities gives a grand total number of ways to be $31688202068279540784000$ or roughly $31.7 \text{ sextillion}$

Just for size reference, one sextillion is roughly equal to $3$ times the amount of gallons of water on Earth (Source)


Edit: I forgot to mention that in this case the orientation of the board is fixed as well. If we want to say that two particular arrangements that only differ by rotating the board $90°$, $180°$, or $270°$ are the same arrangement, then we need to divide our final answer by $4$.