I have a complex vector $S=[S_1,S_2,S_3,S_4]$ with $|S_1|^2+|S_2|^2+|S_3|^2+|S_4|^2=1$. My question is how to bulid a matix $C\in SU(4)$ while
\begin{equation}C= \left( \begin{array}{cccccc} S_1 & S_2 & S_3 & S_4 \\ *&*&*&*\\ *&*&*&*\\ *&*&*&*\\ \end{array} \right) \end{equation}
Many thanks in advance.
For convenience, I'll call your vector $z$ instead. So, we want to construct a unitary matrix whose determinant is $1$ and whose first row is $z^T$. If $z=(c,0,0,0)^T$ for some unit complex number $c$, then clearly the diagonal matrix $C=\operatorname{diag}(c,\bar{c},1,1)$ will do. Suppose $z$ is not a multiple of $(1,0,0,0)^T$. Then $C$ can be constructed easily in a few steps: