How to apply linear independence on the infinitesimals?

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Let $F(x,y,z): \mathbb{R}^{3} \rightarrow \mathbb{R}$, and $dF = \frac{\partial F}{\partial x}dx + \frac{\partial F}{\partial y}dy + \frac{\partial F}{\partial z}dz$.

If $x,y,z$ are linear independent, how to use the defination of the linear independent to proof $\nexists\left(a,b,c\right) \neq \left(\frac{\partial F}{\partial x},\frac{\partial F}{\partial y},\frac{\partial F}{\partial z}\right): dF = adx+bdy+cdz$.

Linear independence is defined on vectors. $dx,dy,dz$ , which are infintesimals, are scalars. Is there any method for appling the defination of the linear independence on them?

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Actually, linear independence is defined in every vector space (or more general module). Here, you are looking at the tangent space which is spanned by the partial derivatives. Since they form a basis of the tangent space, you know that every vector in the tangent space, e.g. $dF$, admits a unique representation as linear combination in the basis. Consequently, $dx, dy, dz$ is the only possibility.