How can I compute the Euler characteristic of a compact surface from its polygonal presentation $\langle S | W_1 , \ldots , W_k \rangle$? I guess that the number of edges is the number of different symbols in $S$, but how to get the number of vertices and the number of faces?
How to compute Euler characteristic from polygonal presentation?
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You can explicitly count the number of equivalence classes of vertices (where two vertices are considered equivalent iff they are to be identified). Edges appear in pairs-to-be-identified, so you get the number of edges by dividing the number of edges on the polygon by $2$ (equivalently, by counting the number of distinct letters appearing in the word). Finally there is a single face (the interior of the polygon).
For example, take this polygonal presentation of a cube (sphere):

There are $8$ equivalence classes of vertices, and $7$ pairs of edges. So the Euler characteristic of the cube is $8 - 7 + 1 = 2.$
Equivalently, by an explicit algorithm you can reduce the presentation to a canonical form (corresponding to the compact surface of genus $g$, orientable or not), and compute the Euler characteristic there (or even use the fact that $\chi(S_1 \# S_2) = \chi(S_1) + \chi(S_2) - 2$, so that you only need the characteristic of the sphere, torus, and projective plane).
If the polygonal presentation contains only one word, the following algorithm works:
Example:
Cube: $S = \langle a, b, c, d, e, f \mid aa^{-1}e^{-1}dd^{-1}gcc^{-1}g^{-1}e f bb^{-1}f^{-1} \rangle$ (c.f. A.P.'s answer)
Adding vertex symbols: $AaBa^{-1}Ce^{-1}DdEd^{-1}FgGcHc^{-1}Ig^{-1}KeLfM bNb^{-1}Of^{-1}A$
Building vertex sets:
Edge $a$: $\lbrace A, C \rbrace$, $\lbrace B, B \rbrace$; Edge $b$: $\lbrace M, O \rbrace$, $\lbrace N, N \rbrace$; Edge $c$: $\lbrace G, I \rbrace$, $\lbrace H, H \rbrace$; Edge $d$: $\lbrace D, F \rbrace$, $\lbrace E, E \rbrace$; Edge $e$: $\lbrace D, K \rbrace$, $\lbrace C, L \rbrace$; Edge $f$: $\lbrace L, A \rbrace$, $\lbrace M, O \rbrace$; Edge $g$: $\lbrace F, K \rbrace$, $\lbrace G, I \rbrace$
Building unions:
$\lbrace A, C \rbrace \cup \lbrace C, L \rbrace \cup \lbrace L, A \rbrace = \lbrace A, C, L \rbrace$, $\lbrace D, F \rbrace \cup \lbrace D, K \rbrace \cup \lbrace F, K \rbrace = \lbrace D, F, K \rbrace$
Resulting disjoint vertex sets:
$\lbrace A, C, L \rbrace$, $\lbrace D, F, K \rbrace$, $\lbrace M, O \rbrace$, $\lbrace G, I \rbrace$, $\lbrace B \rbrace$, $\lbrace E \rbrace$, $\lbrace H \rbrace$, $\lbrace N \rbrace$
The number of disjoint vertex sets is 8. Thus, the number of vertices is 8.