Suppose you have a Lie group $G$ with identity element $g$, then the Lie algebra is isomorphic to the tangent space at $g$, $T_gG$. However, to fully specify the Lie algebra, you also have to define a Lie bracket. For matrix Lie groups, the Lie bracket can be constructed from the commutator, but are there constructions that hold for general Lie groups, just from knowledge of the group $G$ and the exponential map from $T_gG$ to $G$?
To be a bit more specific, does $log(exp(x)exp(y))-log(exp(y)exp(x))$ define a Lie bracket, at least locally?
You have an adjoint action of $G$ on $\mathfrak{g}$ (by conjugation). It gives you (by differentiating) the map $ad$ from $\mathfrak{g}$ to $End(\mathfrak{g})$. Now $(ad(x))(y)=[x,y]$
Also, in terms of $exp$ you have $\log(\exp(tX)exp(tY))=t(X+Y)+t^2[X,Y]+o(t^2)$