If I convert, say, #FF$1919$ to binary, I can do it in groups of three bytes like:
FF: $1111$ $1111$
$19$: $0001$ $1001$
$19$: $0001$ $1001$
So can I write that #FF$1919 =$ $1111$ $1111$ $0001$ $1001$ $0001$ $1001$?
Or do I have to write them as separate bytes like above?
Yes that is absolutely fine. You could have also done it as: $$F: 1111$$ $$F: 1111$$ $$1: 0001$$ $$9: 1001$$ $$1: 0001$$ $$9: 1001$$ and combined in the same way
So $FF1919: 1111\space 1111\space 0001\space 1001\space 0001\space 1001$