Say there is a homomorphism from a group $G_1$ to another group $H$, and there is a homomorphism from $G_2$ to $H$, then there is a homomorphism from $G_1*G_2$ to $H$ induced by the former to homomorphisms? Thanks. (Where $G_1*G_2$ is the free product.)
How to prove the existence of this homomorphism $G_1*G_2\to H$?
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The elements of $G_1*G_2$ look like words whose letters are elements of $G_1$ and $G_2$. By fiat, the identity elements of these two groups are equal in $G_1*G_2$, while any other two elements are distinct. The multiplication tables of $G_1$ and $G_2$ are the same inside $G_1*G_2$ but otherwise there are no relations satisfied between the elements of $G_1$ and $G_2$.
Suppose $\rho: G_1*G_2\to H$ is any group homomorphism. Prove that $\rho$ is determined by its values on $G_1$ and $G_2$. That should inspire you to go in reverse and show that any two maps $G_1,G_2\to H$ can be put together to get a map $G_1*G_2\to H$. How is this map defined?
(The free product satisfies the universal property of coproducts in the category of groups.)
Assuming you mean "group homomorphisms" as opposed to "homotopies"
Let our homomorphisms be $\phi_1:G_1 \rightarrow H$ and $\phi_2:G_2 \rightarrow H$. Elements of the free product $G_1 * G_2$ can be represented as alternating products of elements of $G_1$ and $G_2$. The element $a_1a_2b_1b_2$ where $a_1,b_1 \in G_1$ and $a_2, b_2 \in G_2$ is one such example.
We can construct a homomorphism $\phi: G_1 * G_2 \rightarrow H$ just by mapping an element $g$ to $\phi_1(g)$ if $g \in G_1$ and $\phi_2(g)$ if $g \in G_2$. For example, $\phi(a_1a_2b_1b_2) = \phi_1(a_1)\phi_2(a_2)\phi_1(b_1)\phi_2(b_2) = \phi(a_1a_2)\phi(b_1b_2)$.
It is clear from the above example that $\phi$ is a homomorphism.