How to show that matrices are linearly independent as vectors in $ M_{2×2}(\mathbb C) $ over $ \mathbb C $?

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Let $$ A=\begin{pmatrix} 1 & 2 \\ 1 & 4 \\ \end{pmatrix}, B=\begin{pmatrix} 2 & 3 \\ 3 & 5 \\ \end{pmatrix}, C=\begin{pmatrix} -1 & 1 \\ -2 & -3 \\ \end{pmatrix} ∈ M_{2×2}(\mathbb C). $$ Show that A, B, C are linearly independent as vectors in $ M_{2×2}(\mathbb C) $ over $ \mathbb C $.

How do I show that matrices are linearly independent? And does it matter that it is over $ \mathbb C $? I had an idea that it has something to do with determinants but I'm not sure from there.

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With linear independence for matrices, it is exactly the same as with linear independence for vectors. Hence, the following two statements are equivalent even for matrix spaces:

1) $ (A,B,C) \ \text{is a linearly independent set over} \ \mathbb{C} $

2) $\forall \lambda_i \in \mathbb{C}:\lambda_1 A + \lambda_2B+\lambda_3C=0 \Longrightarrow \lambda_1=\lambda_2=\lambda_3=0$.

To show this, one can also proceed very similarly like for vectors. For your specific problem, the first equation of 2) would yield a linear, homogenous system of 4 equations with 3 variables. If this system has a non-trivial solution, your matrices are linearly dependent; if not, they aren't.

Edit: Also, in the general case it does matter whether you seek for linear independence over $\mathbb{R}$, $\mathbb{C}$ or some other field. The scalars $\lambda_i$ are namely then element of different sets, and for $\lambda_i \in \mathbb{C}$ it might be possible to find such a non-trivial solutions, whereas it might be impossible for $\lambda_i \in \mathbb{R}$. An example for this happening is the following: $$ A=\pmatrix{1 & 1 \\ 1 & 0} \text{and} \ B=\pmatrix{i & i \\ i & 0} \in M_{2 \times 2}(\mathbb{C}) $$ are linearly independent over $\mathbb{R}$, but aren't over $\mathbb{C}$.

Edit 2: As mentioned in the comments, it is also possible to write them as vectors of $\mathbb{C}^4$. This is because the mapping $$ \phi: \left\{ \begin{array}{ll} M_{2 \times 2}(\mathbb{C}) \to \mathbb{C}^4 \\ \pmatrix{a & b \\ c & d} \mapsto \pmatrix{a \\ b \\ c \\ d} \\ \end{array} \right. $$ is an isomorphism. Linearity is quite easy to check and bijectivity follows from the fact that $$ \ker(\phi)=\left\{\pmatrix{0 & 0 \\ 0 & 0}\right\} $$ and every element of $\mathbb{C}^4$ has a unique inverse image. In your specific question, this wouldn't help a lot nevertheless, because you wouldn't get a square matrix by writing $\phi(A)$, $\phi(B)$ and $\phi(C)$ together into a matrix. Therefore, you can't apply the determinant and can just check the linear independence by the first method I proposed.