I want to show explicitly that $L^2[0,1]$ subspace of $L^1[0,1]$ has no internal points.
If S subspace of X, I have the following result:
S = X if and only if the interior of S $\neq \emptyset$
Then to prove that the interior is empty, I just need to prove S is different from X.
Can I just pick $f(x) = \frac{1}{\sqrt{x}}$ and say that it belongs to $L^1$ but not to $L^2$ and be done?
Is there something that I am missing?
No, you are not missing anything. If $X,Y$ are normed spaces, and $X$ is a proper subspace of $Y$, then $X$ has empty interior relative to $Y$. So if you show that $L^2[0,1]$ is a proper subspace of $L^1[0,1]$, you are done. The function $f(x)=\frac{1}{\sqrt{x}}$ is indeed an element of $L^1[0,1]$ that does not belong to $L^2[0,1]$.