It looks pretty easy but I can't see a way out of this problem.
If $7|100a+b$, prove $7|2a+b$, $a, b \in \mathbb{Z}$
We have that
$$100a+b\equiv 0 \mod 7$$
$$\implies 100a-7*14a+b\equiv 0 \mod 7$$
$$\implies 2a+b\equiv 0 \mod 7$$
Note that $7|(100a+b)$ and also $7|7a$.
Hence $7|(14\times 7a) \implies 7|98a$.
Thus, we can say that $\boxed {7|(100a+b)-98a \implies 7|(2a+b)}$.
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We have that
$$100a+b\equiv 0 \mod 7$$
$$\implies 100a-7*14a+b\equiv 0 \mod 7$$
$$\implies 2a+b\equiv 0 \mod 7$$