If I've got a group $G=\langle a,b\rangle$ where $a$ and $b$ are permutation from $S_8$, and a subgroup of $G$ $N=\langle a^2, b^2\rangle$ (which is in the center of $G$). I have to prove that the quotient group $G/N$ is abelian.
I know that a group is abelian if the elements of it can be commuted between them. But I don't know how to do it with the quotient subgroup, I mean I don't really know which are the elements from $G/N$ (I think that they are the left cosets but I'm making a mess)
This is false! You cannot expect the result to be true for all subgroups $G$ satisfying your conditions.
Here is a counterexample. Let $a=(1 \ 2)(3 \ 8) (4 \ 7)(5 \ 6), b=(2 \ 8)(3 \ 7)(4 \ 6)$.
Fact. $G=\langle a,b\rangle$ is isomorphic to $D_8$.
To see this, label the vertices of a regular octogon, putting the first one on the $x$-axis of the real plane. If $r$ is the rotation with center $O$ and angle $\dfrac{2\pi}{8}$ and if $s$ is the orthogonal reflection with respect to the $x$-axis, then the permutations induced by $r\circ s$ and $s$ on the eight vertices are exactly $a$ and $b$ (modulo eventual mistakes in my computations...)
Now $D_8=\langle r,s\rangle=\langle rs,s\rangle$. Hence, the group $D_8$, viewed as a subgroup of $S_8$ is $D_8=\langle a,b\rangle$.
To conclude, observe that $a^2=b^2=Id$, so $N=\{Id\}\subset Z(G)$, and $G/N=G/\{Id\}\simeq G$ is not abelian.
So, you have to specify what is the group $G$ you are working with, since the property you are looking for in not true in general.
To answer your original question, as @Ewan suggested, your quotient group (whaterver it is) is generated by the classes $\alpha=aN$ and $\beta=bN$. It is then clear that $G/N$ is abelian if and only if $\alpha\beta=\beta\alpha$. Using the definition fo the group law on $G/N$ (which is well-defined, since a subgroup of the center is normal), you get $abN=baN$, that is $aba^{-1}b^{-1}N=N$, which is equivalent to $aba^{-1}b^{-1}\in N$.
Hence, to prove that $G/N$ is abelian in your specific case, you have to check whether $aba^{-1}b^{-1}\in N$ or not. Unfortunately, since it is false in general and you did not tell who are $G,a$ and $b$, it is not possible to tell you more than that.