Suppose $D+A$ is hermitian matrix, and $D$ is a diagonal matrix. Then $A$ is a hermitian matrix as well.
Since $D+A$ is a hermitian matrix, there exists $P$ such that $P^{-1}(D+A)P$ is a diagonal matrix.
The question is, how do I prove that same $P$ also diagonalizes $A$ such that $P^{-1}AP$ is a diagonal matrix? Or is there a counterexample?
No. For any $n>1$, let $P$ be any entrywise nonzero unitary matrix, $S$ be any real diagonal matrix, $D$ be any real diagonal matrix with distinct diagonal entries and $A=PSP^{-1}-D$. Then
However, $P^{-1}AP$ cannot possibly be diagonal. Suppose the contrary. Then both $D$ and $\Lambda=P^{-1}DP=S-P^{-1}AP$ are diagonal. As they are similar matrices, the diagonal entries of $\Lambda$ are obtained from a permutation of those of $D$. Hence $P^{-1}DP=MDM^T$ for some permutation matrix $M$. It follows that $D(PM)=(PM)D$. However, by definition, all diagonal entries of $D$ are distinct. Hence $PM$ must be a diagonal matrix. In turn, $P$ is the product of a permutation matrix and a diagonal matrix. But this is impossible, because $P$ was chosen to be entrywise nonzero. Hence $P^{-1}AP$ is not diagonal.