I've tried to use the limit test: $\lim_{n \rightarrow \infty} \frac{a_n}{b_n} = C$ in the series of $a_n$ and $\frac{a_n}{a_1+a_2+...+a_n}$ but it was inconclusive.
The question does not especify the sign of $a_n$ but proving it for positives would already help.
I think the sign can change as long as the partial sums never get to be zero. Like if the series has only negative numbers the result seems to stil hold.
Show that the series $\sum_{n=1}^\infty \frac{a_n}{S_n}$ diverges
Suppose the $a_n$ are non-negative. To prove that the series diverges to $+\infty$, it is enough to prove that for every $N\in\Bbb N$, there exists $N'>N$ such that $$\sum_{n=N}^{N'}\frac{a_n}{a_0+\cdots+a_n}\geq \frac12$$ So fix $N>0$, and notice that for every $M>N$ $$\sum_{n=N}^{M}\frac{a_n}{a_0+\cdots+a_n}\geq\sum_{n=N}^{M}\frac{a_n}{a_0+\cdots+a_{M}}=\frac{a_N+\cdots+a_{M}}{a_0+\cdots+a_{M}}=1-\frac{C}{a_0+\cdots+a_{M}}$$ where $C=a_0+\cdots+a_{N-1}$ is a constant. The second term is of the form "constant over something that tends to infinity" and so tends to $0$, and eventually we get a minoration by $\frac12$, showing that the series diverges to infinity.