Stephen Abbott has a an exercise in Chapter 1 (1.2.12) that suggests that one cannot use induction to prove that a countable union of countable sets is countably infinite.
One answer is that $n={}$infinity cannot be demonstrated via induction, as inifinity is not a natural number. This seems sketchy. Rudin in chapter 2 clearly distinguishes the use of inifinity symbol for a union of sets to indicate a countably infinite union of sets and distinguishes it from the infinity used to extend the reals.
All of this also appears to ignore the fact $N$ is countably infinite by definition. Therefore any bijection with $N$ is also proved for countably infinite cases.
So why cannot induction be used to argue countable union of countable sets is countable?
Here is an example where induction is being used in the context of countably infinite sets. Using induction to prove that the infinite set of polynomials is countably infinite
Induction can be used to prove that the union any fixed, arbitrarily large, but finite, number of countable sets is countable.
This statement is emphatically not the same as saying that the union of countably infinitely many countable sets is countable.
Somewhat more formally, suppose that $A_i$ is a countable set for each $i\in\mathbb N$. You can use induction to prove that the set $$\bigcup_{i=1}^n A_i$$ is countable for any given $n\in\mathbb N$. But this does not imply that the set $$\bigcup_{i=1}^{\infty} A_i$$ is countable!
[Spoiler alert: using the axiom of choice, you can prove that the union of countably many countable sets is actually countable. You just cannot do that using induction alone.]