Inequality with Sum of Binomial Coefficients

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My friend noticed that for $n>12$, we have the following pattern in the binomial coefficients.

$$\sum_{i=0}^{\lfloor n/3 \rfloor}\binom{n}{i} < \binom{n}{\lfloor n/3 \rfloor + 1}$$ $$\sum_{i=0}^{\lfloor n/3 \rfloor + 1}\binom{n}{i} > \binom{n}{\lfloor n/3 \rfloor + 2}$$

We've checked these inequalities up to $n=200$ with a computer, but have not been able to come up with a proof.

Attempt: We've attempted a asymptotic approach using Stirling approximation $$\binom{n}{k} \approx \sqrt{\frac{n}{2\pi k (n-k)}} \frac{n^n}{k^k (n-k)^{n-k}}$$ but approximating with an integral doesn't seem to help very much, as it seems quite hard to compare $$\int_0^{n} \sqrt{\frac{3n}{2\pi k (3n-k)}} \cdot \frac{(3n)^n}{k^k (3n-k)^{3n-k}} dx \quad \text{and} \quad \sqrt{\frac{3}{4\pi}} \frac{3^{3n}}{2^{2n}}$$

One thing I have realized which seems important is that $$2 \binom{3n}{n} \approx \binom{3n}{n+1} $$ However, I have not been able to work this into a proof. Any ideas?

2nd Attempt: Using B. Mehta's linked post, in particular this inequality, $$\sum_{i=0}^k \binom{n}{i} \leq \binom{n}{k} \frac{n-(k-1)}{n-(2k-1)}$$ subbing in $k=\lfloor\frac{n}{3}\rfloor$, we can almost get the inequality as follows $$\sum_{i=0}^{\lfloor n/3 \rfloor} \binom{N}{i} \leq \binom{n}{\lfloor n/3 \rfloor} \frac{n-\lfloor n/3 \rfloor + 1}{n - 2 \lfloor n/3 \rfloor + 1}$$ Now we can use that $\binom{n}{k+1} = \binom{n}{k} \frac{n-k}{k+1}$ to get $$\sum_{i=0}^{\lfloor n/3 \rfloor} \binom{N}{i} \leq \binom{n}{\lfloor n/3 \rfloor + 1}\frac{\lfloor n/3 \rfloor+1}{n-\lfloor n/3 \rfloor}\frac{n-\lfloor n/3 \rfloor + 1}{n - 2 \lfloor n/3 \rfloor + 1}$$ But unfortunately, the inequality $$\frac{\lfloor n/3 \rfloor+1}{n-\lfloor n/3 \rfloor}\frac{n-\lfloor n/3 \rfloor + 1}{n - 2 \lfloor n/3 \rfloor + 1} \leq 1$$ does not hold for any multiples of $3$. Any other ideas?

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It looks that the same was proven in the paper E.L.Johnson, D.Newman, K.Winston. An Inequality on Binomial Coefficients. Annals of Discrete Mathematics 2 (1978) 155-159. https://doi.org/10.1016/S0167-5060(08)70330-3 page 1 page 2 page 3 page 4 page 5

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This is partially a comment that is slightly too long. In the Math Overflow article, we want to bound

$$ {{N \choose k} + {N \choose k-1} + {N \choose k-2}+\dots \over {N \choose k}} = {1 + {k \over N-k+1} + {k(k-1) \over (N-k+1)(N-k+2)} + \cdots} $$

The author chooses to use a geometric series as an upper bound starting with the first term. However, we can slightly delay the geometric series to get a smaller upper bound as follows:

$$ 1 + {k \over N-k+1} + {k(k-1) \over (N-k+1)(N-k+2)} + \cdots = \\1 + \frac{k}{N-k+1} \left(1 + \frac{k-1}{N-k+2} + \frac{(k-1)(k-2)}{N-k+2(N-k+3)} \right) + \cdots$$ Using a geometric series for an upper bound in the inner parenthesis gives us an upper bound of $$ \dbinom{N}{k} \left(1 + \frac{k}{N-k+1} \cdot \frac{N-k+2}{N-2k+3} \right). $$ We can easily check that for large enough $N$, $$1 + \frac{k}{N-k+1} \cdot \frac{N-k+2}{N-2k+3} < \frac{N-(k-1)}{N-(2k-1)}. $$ Finally we can check that the steps used by the OP in the 2nd attempt portion of the question does go through if $N = 3k$ (which was an issue last time) for large enough $N$. This is just some algebraic manipulations so I won't post it here. Hopefully I haven't made an error.