The exponent $A \sin{x}$ has a single maximum on $[0, \pi]$, so it's natural to use the following method: isolate the extremum point on a small interval $(\pi/2 - \delta_A, \pi/2 + \delta_A)$, express the asymptotic value there and just prove that the remaining integral has smaller order of magnitude (for some suitable $\delta_A$). I believe it should be called saddle-point method or something like that.
The first step didn't cause me too much trouble: using the Taylor expansion of the exponent around $\pi/2$ I was able to conclude that $$ \int\limits_{\pi/2 - \delta_A}^{\pi/2 + \delta_A} e^{A \sin{x}} dx = (1 + o(1)) \sqrt{2\pi} \frac{e^A}{\sqrt{A}}, $$ provided $A \delta_A^3 \underset{A \to \infty}\longrightarrow 0$ and $A \delta_A^2 \underset{A \to \infty}\longrightarrow \infty$.
However, I had a hard time proving that remaining integral, namely, $2 \cdot \int_0^{\pi/2 - \delta_A} e^{A \sin{x}} dx$ has a smaller order of magnitude. I tried using an obvious estimate $A\sin{x} \leqslant Ax$ but it has proven itself too rough. Expanding couple more terms didn't get me anywhere either: integrals involved become just too complicated to even start to estimate and/or evaluate.
Note that $$ \int_0^{\pi /2 - \delta _A } {{\rm e}^{A\sin x} {\rm d}x} \le \frac{\pi }{2}{\rm e}^{A\sin (\pi /2 - \delta _A )} = \frac{\pi }{2}{\rm e}^A {\rm e}^{A(\cos (\delta _A ) - 1)} . $$ By Taylor approximation and your assumptions, we can assert that $$ A(\cos (\delta _A ) - 1) = - \frac{1}{2}\delta _A^2 A + \mathcal{O}(\delta _A^3 A ) \to - \infty $$ as $A\to+\infty$. If, in addition, $$ \delta _A^2 A \gg \log A $$ then $$ {\rm e}^{A(\cos (\delta _A ) - 1)} = o\!\left( {\frac{1}{{\sqrt A }}} \right). $$ For instance, $$ \delta _A = \frac{{\log A}}{{\sqrt A }} $$ is an appropriate choice that satisfies all the requirements.