I'm learning about Rings, commutative rings, IDs, UFDs, etc with each being a subset of the predecessor, and I'm now trying to find an ID that is not a UFD
I understand $\mathbb Z[\sqrt{-5}]$ is an Integral domain, but not a UFD, but I'd like a bit of explanation as to why?
First: $\mathbb Z[\sqrt{-5}] = x + y \sqrt{-5}$ where $x, y \in \mathbb C$
What is this 'thing'. I'd like to understand it in words... I initially thought it was every multiple of $\sqrt{-5}$ in the complex plane but I can see that's not true, so how would you explain it in words?
Does this exist at every point in $\mathbb C$?
And finally, can you please explain a simple case of it where it is an ID but not a UFD?
Thanks a lot!

You misunderstood the definition: $$ \Bbb{Z}[\sqrt{-5}] := \left\{ a + b \sqrt{-5} : a,b \in \Bbb{Z} \right\} $$ This is an integral domain because $$ (a + b\sqrt{-5}) (c + d\sqrt{-5}) = ac - 5bd + (ad + bc)\sqrt{-5} $$ is $0$ if and only if $(a,b) = (0,0)$ or $(c,d) = (0,0)$, as a direct consequence of $\Bbb{Z}$ being an integral domain[1]. Indeed, suppose that these were (non-zero) zero-divisors. Then neither $a$ or $b$ can be zero, otherwise both $c$ and $d$ are forced to be $0$ because $\Bbb{Z}$ has no zero-divisors. But if $a \neq 0$ then (in $\Bbb{Z}$) $$ \begin{cases} ac = 5bd\\ ad = -bc \end{cases} \quad \Rightarrow \quad \begin{cases} acd = 5bd^2\\ adc = -bc^2 \end{cases} \quad \Rightarrow \quad b(c^2 + 5d^2) = 0 $$ which is absurd because $5d^2$ is not a square unless $d \neq 0$ and there are no zero-divisors in $\Bbb{Z}$.
[1] I added this proof to make it clear that $\Bbb{Z}[\sqrt{-5}]$ is a domain if and only if $\Bbb{Z}$ is a domain. A quicker way to see that $\Bbb{Z}[\sqrt{-5}]$ must be a domain would be to see it as a sub-ring of $\Bbb{C}$.
To see that it is not a UFD all you have to do is find an element which factors in two distinct ways. To this end, consider $$ 6 = 2 \cdot 3 = (1+\sqrt{-5})(1-\sqrt{-5}) $$ and prove that $2$ is irreducible but doesn't divide $1 \pm \sqrt{-5}$. This is enough because in a UFD every irreducible element is prime.
Define $N(a+b\sqrt{-5}) := a^2+5b^2$ (this is called the norm of $a+b\sqrt{-5}$) and observe that if $x,y \in \Bbb{Z}[\sqrt{-5}]$ are such that $x \mid y$, then $N(x) \mid N(y)$. In particular, the invertible elements are exactly the elements of norm $1$. This means that if $2$ isn't irreducible, then there must be some non-invertible $x \in \Bbb{Z}[\sqrt{-5}]$ such that $N(x) | 4$ and $x \neq \pm 2$. But $a^2 + 5b^2 = 2$ has no solutions $(a,b) \in \Bbb{Z}^2$ and the only solutions of $$ a^2 + 5b^2 = 4 $$ with $a,b \in \Bbb{Z}$ are $(a,b) = (\pm 2,0)$. Finally, you can easily see that there are no $a,b \in \Bbb{Z}$ such that $$ 1 + \sqrt{-5} = 2 (a + b\sqrt{-5}) = 2a + 2b\sqrt{-5} $$ and similarly for $1 - \sqrt{-5}$.