How can I calculate below integrals:
$$\int \hat{r}_i\ \hat{r}_j\ \hat{r}_k\ \hat{r}_l \ d\Omega$$
in which $d\Omega =\sin(\theta) \ d \theta\ d\phi $ is the surface element of the sphere and $\hat{r}_i$ indicates $i$'th component of unit vector r. For ex. $\hat{r}_1= \sin \theta \ \cos \phi$
Could anyone help me?
Clearly the surface integral vanishes if it has a factor of any component to an odd power. We can always write the surface integral in spherical coordinates, aligning the $z$ axis with one of the indices appearing to the $4$-th or $2$-nd power.
We can also make the substitution $u = \cos \theta$ where $du = -\sin \theta\, d\theta$.
Thus when $i=j=k=\ell$ the integral is $$ -\int_1^{-1}2\pi u^4 du=\frac45\pi $$ (the $2\pi$ comes from thje integral over $\phi$.)
And when $i=j$ and $k=\ell\neq i$ (and all other pairings of the like nature) the integral is $$ -\int_{\phi = 0}^{2\pi}\cos^2\phi\int_1^{-1}u^2(1-u^2) du $$ where we have used $sin^2 = 1-\cos^2$ to turn the $\sin^2\theta$ into $(1-u^2)$.
The $d\phi$ integral is easy if you remember that over a full cycle, the average value of $\cos^2\phi$ is $\frac12$. We are left with $$ \pi \int_{-1}^1(u^2-u^4)\,du=\pi\left( \frac23-\frac25 \right)=\frac2{15}\pi $$
Finally, we need to turn these into a unified expression involving the indices $i,j,k,\ell$, which is allowed to used the Kroenecker delta $\delta_{mn} = 1$ if $m=n$ and $0$ otherwise.
The integral must then be of the form $$ \int \hat{r}_i\hat{r}_j\hat{r}_k\hat{r}_\ell= \frac2{15} \pi (\delta_{ij}\delta_{k\ell}+\delta_{ik}\delta_{j\ell}+\delta_{i\ell}\delta_{jk}) + \lambda \delta_{ij}\delta_{ik}\delta_{i\ell} $$ where $\lambda$ is chosen to make the all-indices-equal answer come out to $\frac45\pi$. When all four indices are equal the first term becomes $\frac6{15}\pi = \frac25 \pi$ so $\lambda$ must be $\frac25$. The answer is $$ \int \hat{r}_i\hat{r}_j\hat{r}_k\hat{r}_\ell= \frac2{15} \pi (\delta_{ij}\delta_{k\ell}+\delta_{ik}\delta_{j\ell}+\delta_{i\ell}\delta_{jk} + 3\, \delta_{ij}\delta_{ik}\delta_{i\ell}) $$