I can evaluate the limit with L'Hospital's rule:
$\lim_{n\to\infty}n(\sqrt[n]{4}-1)=\lim_{n\to\infty}\cfrac{(4^{\frac1n}-1)}{\dfrac1n}=\lim_{n\to\infty}\cfrac{\dfrac{-1}{n^2}\times 4^{\frac1n}\times\ln4}{\dfrac{-1}{n^2}}=\ln4$
But is there any way to do it without using L'Hospital's rule?
If $f(x)=4^x$, then $f'(x)=\log(4)4^x$ and, in particular, $f'(0)=\log(4)$. In other words,$$\lim_{h\to0}\frac{4^h-1}h=\log(4)$$and therefore$$\lim_{n\to\infty}\frac{4^{1/n}-1}{1/n}=\log(4),$$which is the same thing as asserting that$$\lim_{n\to\infty}n\left(\sqrt[n]4-1\right)=\log(4).$$Note that all that I used was the definition of derivative together with the knowledge of $(4^x)'$.