Is it possible to use Leibniz Criteria to find out if a positive series converges?

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I have to study the convergence of a positive series. I wanted to know if Leibniz criteria could be applied even though it's not an alternating series, as long as it doesn't violate the other two hypothesis.

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No. Look at $\sum_{n=1}^\infty \frac{1}{n}$. The terms $1/n$ monotonically decrease to zero, but the series diverges.