Are $\mathbb{C}^2$ and $\mathbb{R}^4$ isomorphic to one another? Two vector spaces are isomorphic if and only if there exists a bijection between the two. We can define the linear map $T: \mathbb{C}^2 \mapsto \mathbb{R}^4$ as
$$ T\left(\left[\begin{array}{cc} a + bi \\ c + di \end{array}\right]\right) = \left[\begin{array}{cccc} a \\ b \\ c \\ d \end{array}\right] $$
Does this bijection suffice to show that they're isomorphic?
If you are talking about isomorphism as vector spaces over $\mathbb{R}$ then yes, you are correct. However a bijection between two spaces is not enough for them to be isomorphic ( for example $\mathbb{R}$ is bijectable with $\mathbb{C}$ but they are not isomorphic as vector spaces over $\mathbb{R}$. What you need is a bijection that is also a linear function