I was reading the following How do i prove that every open set in $\mathbb{R}^2$ is a union of at most countable open rectangles?
The answer by "user4594" basically considers a k-cell with rational endpoints, and I am guessing that when he says that "E would be the union of these cells" the axiom of choice is needed because for each x there may be more than one k-cell with rational endpoints.
Am I correct?
You could actually take all rectangles with rational endpoints containing $x$, since there are at most countably many of them, so you don't need choice.
Anyway, choice on subsets of a countable set is provable without the full Axion of Choice.