let $V$ be a vector space over the field $F$ and let $V'$ denote the dual of $V$, that is, the set of all linear maps from $V$ to $F$ equipped with the scalar product $(c\cdot f)(v) = c\cdot(f(v))$ and vector sum $(f+g)(v) = f(v)+g(v)$.
Is it always the case that $V'$ is isomorphic to $V'''$? Moreover, is it always the case that the natural homomorphism is an isomorphism between $V'$ and $V'''$? That is, the natural homomorphism being the map $\phi$ defined by $\phi(f)=g_f$ where $g_f$ is defined by $g_f(x) = x(f)$ and where $x$ is in $V''$ and f is in $V'$.
If this is not the case I would like a proof, otherwise I'd like a counter example. Thanks