Let $S$ be the abstract simplicial complex with facets $\{A,B,D\}$, $\{A,C,D\}$, $\{B,C,D\}$. Its geometric representation is homeomorphic to a disc:
In this picture, the geometric representation of the sub-complex $T$ with facets $\{A,B\}$, $\{B,C\}$, $\{C,A\}$ maps to the boundary of the disc. So we can say that "the boundary of $S$ is $T$".
My question is: is this notion of "boundary" well-defined? That is, given any abstract complex $S$ with geometric representation homeomorphic to a ball, is there a unique subcomplex $T\subseteq S$, such that the geometric representation of $T$ equals the boundary of that ball?

You could define it as follows:
Let $S$ be an abstract simplical complex. Then define $\partial S=\{A\in S\colon \exists!B\in S, A\subsetneq B\}$ where $\exists!$ means "There is a unique".
The idea behind this definition is as follows:
But I do not know if this definition is standard.
You can then try to prove all properties you require.