Is there a plane that contains both $L_1$ and $L_2$? If so find its equation
These are lines.
$L_1$ is the line through points $(0,1,1)$ and $(-1,2,1)$
The direction vector is $(-1,2,1)-(0,1,1)=(-1,1,0)$
So $(x,y,z)=(0,1,1)+t(-1,1,0),t\in\mathbb{R}$
$L_2$ is a line that is orthogonal to the plane $\pi$, which has the normal vector $(-2,2,2)$, and $L_2$ passes through the point $(4,0,1)$
And so we have that $(x,y,z)=(4,0,1)+k(-2,2,2),k\in\mathbb{R}$
The question says that if there is a plane that contains both $L_1$ and $L_2$, find its equation.
For a plane we need $3$ points. How do I found $3$ points that are on both lines?
If I equate I get that:
$(0,1,1)-(4,0,1)=t(-1,1,0)-k(-2,2,2)$
which means
$(-4,1,0)=t(-1,1,0)-k(-2,2,2)$
Two lines can intersect in zero places, one place, or infinitely many. In this case, it's impossible to find three intersections.
To define a plane, we need three points, and they need to be non-collinear. Imagine I gave you the points $(0, 0, 1), (0, 0, 2), (0, 0, 3)$ in $\mathbb{R}^3$ and told you to find a plane which contained them. Then any plane which contains the $z$-axis would work -- for example, both $x = 0$ and $y = 0$, and many other planes.
You can find three non-collinear points by taking two points from one line and the third from the other.