I'm looking for a series of rational numbers that approach $\pi$ that are all non-negative. In addition, I also want this series to have a general rule. So something like $\dfrac31+\dfrac1{10}+\dfrac4{100}+\ldots$ is not gonna cut it.
Does such a series exist?
We know what the Taylor series for $\tan^{-1}(x)$ is the following.
$$ \tan^{-1}(x)=\sum_{n=0}^{\infty} (-1)^n \dfrac{x^{2n+1}}{2n+1} $$
We also know that $\dfrac{\pi}4 = \tan^{-1}(1)$. So:
$$ \pi = \sum_{n=0}^{\infty} (-1)^n \dfrac{4}{2n+1} $$
So you can just take the sequence of rational numbers that converge to $\pi$ as:
$$ a_N = \sum_{n=0}^{N} (-1)^n \dfrac{4}{2n+1} $$
This follows the same comment mentioned by @JMoravitz.