I have a question that asks me to differentiate $f(x) = e^5$. This looks like differentiating a constant. So the answer is 0.
But I'm confused about the proof withthe definition of a deriative:
Don't we have an indeterminate limit since $\lim_{h \to 0} \frac{c-c}{h} = \frac{0}{0}$?
Or is the right way to think about this is that the numerator is 0 but the denominator is never really quite 0 and so the limit as a whole is 0?

No, $c-c = 0$ always, even prior to letting $h$ go to zero. So you have $$ \lim_{h \rightarrow 0} \frac{c-c}{h} = \lim_{h \rightarrow 0} \frac{0}{h} = \lim_{h \rightarrow 0} 0 = 0 \text{.}$$
That is, you take the limit of the constant expression zero.
Don't try to do "everything at once". You must evaluate inner nested expressions before starting to evaluate their enclosures. In this case, evaluate the fraction as completely as possible, then take the limit. Correctly evaluating nested expressions from the inside to the outside will be very important when you have nested limits.